2025

DETERMINATION OF THE MINERAL ELEMENT, PROXIMATE CONTENT, PHYTOCHEMICAL COMPOSITION AND THE ANTIBACTERIAL PROPERTIES OF THE AQUEOUS AND ETHANOLIC EXTRACT OF Citrus sinensis ON SOME BACTERIAL ISOLATES

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Plants have long been used as medicine to cure a wide range of illnesses and humans have depended on nature to meet their basic needs. This study was aimed at determining the mineral content, proximate content, phytochemical composition and the antibacterial properties of the aqueous and ethanolic extract of citrus sinensis on some bacterial. The aqueous and ethanolic extracts were evaluated for mineral elemental analysis, proximate content and phytochemical properties using the method of A.O.A.C. Antibacterial activity was evaluated using an agar well dilution techniques against five bacterial isolates using the Mueller Hinton Agar (MHA) method. The minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) of the extract were determined using the MIC and MBC. The mineral element of Citrus sinensis of aqueous and ethanolic extract for Sodium (Na) was (250.333 ± 0.333 mg/kg) and (260.300 ± 0.3111 mg/kg), Potassium (K) (3415.667 ± 2.500 mg/kg) and (2215.060 ± 2.400) mg/kg, Calcium (Ca) (1.412.077± 1.400 mg/kg) and (1,521.047 ± 1.453 mg/kg), Phosphorus (P) (0.2100 ± 0.005 mg/kg) and (0.1900± 0.005 mg/kg), Iron (Fe) (1.1400 ± 0.004 mg/kg) and (1.2400 ± 0.009 mg/kg), Nitrogen (N) (0.1400 ± 0.001 mg/kg) and (1.2000 ± 0.009 mg/kg), Magnesium (Mg) (129.100± 0.700 mg/kg) and (131.000± 0.577 mg/kg). The result for proximate content of aqueous and ethanolic extract of Citrus sinensis showed varying composition of moisture content, ash content, crude fibre, crude fat, protein and carbohydrate. The qualitative phytochemical result revealed the presence of phenols, terpenoids, alkaloids, eugenols, flavonoids, tannins, and reducing sugars. The quantitative phytochemical result revealed the presence of alkaloid to be (5.4063 ± 0.2985) for aqueous and (6.3427±0.329) for ethanolic, total saponins, (5.9620 ± 3.6112) for aqueous and (7.0867±0.002) for ethanolic, total phenolic, (0.2077 ± 0.0012) for aqueous and (0.2140±0.001) for ethanolic, total tannins (10.1533 ± 0.0023) for aqueous and (12.7747±0.161) for ethanolic and for total flavonoids, (6.9993 ± 0.0127) for aqueous and (6.5827±0.031) for ethanolic. The antibacterial activity of the crude extract against selected bacterial isolates was also evaluated using the MHA method. It was demonstrated that at a concentration of 200 mg/kg of both the aqueous and ethanolic extract, the extract of Citrussinensis expressed bactericidal potential against the bacterial isolates. The result from this research shows the potency of the extract of Citrus sinensis being able to the utilized for drug formations with antibacterial effects
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MINERAL ANALYSIS AND COMPARATIVE PHYTOCHEMICAL INVESTIGATION OF THREE EXTRACT OF Tetrapleura Tetraptera

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This study examined the mineral composition and phytochemical profile of Tetrapleura tetraptera fruit pods. The fruit pod was purchased from Uselu market, dried and extracted by maceration method using aqueous, methanol and hexane solvents. The elemental composition was analyzed with a portion of the powdered sample using g X-ray fluorescence spectroscopy (XRF) while phytochemical screening of the three extracts was done via standard methods. Mineral analysis revealed potassium (28.317%) as the most abundant element, followed by calcium (12.962%), magnesium (7.656%), and aluminum (6.413%). Moderate amounts of
Sulphur (1.652%) and chlorine (2.412%) were also detected, while iron was present at a relatively low concentration (1.502%). The dominance of potassium and calcium highlights the fruit’s nutritional potential for maintaining electrolyte balance, bone development, and muscle function. Magnesium and aluminum further contribute to enzymatic activities and possible medicinal value, though the low iron content indicates limited benefit for hemoglobin synthesis and oxygen transport. Phytochemical screening showed that alkaloids, eugenol, and reducing sugars were present across all extracts. Glycosides, flavonoids, tannins, phenolics, and terpenoids were prominent in methanol and aqueous extracts, while hexane extracts yielded fewer polar compounds. Steroids were absent in all extracts. These results confirm that solvent polarity strongly influences phytochemical extraction, with polar solvents yielding a broader spectrum of bioactive constituents
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co-supervisor

NE AGGREGATE WITH PERIWINKLE SHELL IN SANDCRETE BLOCKS

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The increasing demand for sustainable and environmentally friendly construction materials has prompted the exploration of alternative waste materials for use in concrete production. This study investigates the partial replacement of fine aggregate with periwinkle shell in concrete as a means of reducing construction costs, conserving natural resources, and promoting waste utilization. The research evaluates the effects of incorporating varying percentages of processed periwinkle shell as a substitute for fine aggregate on the properties of concrete.
Concrete mixes were prepared with different replacement levels of fine aggregate using periwinkle shell, while a control mix containing conventional materials was also produced. Standard laboratory tests were conducted to determine the workability, density, compressive strength, and durability characteristics of the concrete specimens. The results indicate that the inclusion of periwinkle shell influences the fresh and hardened properties of concrete. Workability generally decreased with increasing replacement levels, while compressive strength showed acceptable performance at lower replacement percentages. The density of the concrete also reduced, suggesting the potential for producing lightweight concrete.
The findings reveal that periwinkle shell can be effectively utilized as a partial replacement for fine aggregate in concrete production without significantly compromising structural performance when used within optimal replacement limits. The study concludes that the use of periwinkle shell contributes to sustainable construction practices by reducing environmental waste and the dependence on natural sand resources. It is recommended that partial replacement levels within the optimum range be adopted for non-critical and selected structural applications
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A CRITICAL ANALYSIS OF THE LEGAL FRAMEWORKS OF INVESTMENT BANKING IN NIGERIA.

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Law is not confined to the regulation of criminal conduct or the enforcement of contractual obligations. Rather, it plays a broader role in regulating various aspects of society, including economic and financial activities. One such area is the capital market, which operates within the wider field of investment banking and has historically been subject to legal control. The regulation of investment banking has evolved through legislative measures aimed at ensuring market stability and protecting investors. Examples include the Glass–Steagall Act of 1933, enacted following the 1929 stock market crash, the Gramm–Leach–Bliley Act of 1999, and Nigeria’s Investment and Securities Decree of 1979, now replaced by the Investment and Securities Act, 2007. These laws demonstrate the importance of legal frameworks in governing capital market operations. In Nigeria, investment banking and capital market activities are regulated by statutory bodies established to ensure compliance with industry standards and to safeguard investors’ interests. Key regulatory institutions include the Corporate Affairs Commission (CAC), responsible for company registration and legal personality; the Securities and Exchange Commission (SEC), which regulates securities transactions and public offers; and the Central Bank of Nigeria (CBN), which promotes financial system stability. This study examines the legal framework regulating investment banking in Nigeria, with particular focus on investor protection, the prevention of practices such as insider trading, the enforcement of regulatory sanctions, and the use of dispute resolution mechanisms, including court proceedings and alternative dispute resolution (ADR). The study highlights the role of law in promoting transparency, accountability, and confidence in Nigeria’s capital market.
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co-supervisor

IMPLEMENTATION OF SMART BATTERY MANAGEMENT SYSTEM

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A Battery Management System (BMS) is an electronic control system that monitors and manages rechargeable battery packs. Secondary batteries are commonly used as the storage of energy produced by solar panels. However, the utilization of a battery without proper management can cause damage due to overcharging and over-discharging.
The BMS continuously monitors cell voltages, current, temperature, and state of charge while protecting potentially damaging conditions such as overcharging, over-discharging, excessive current, and temperature extremes. Advanced systems incorporate cell balancing to maintain uniform charge distribution across multiple cells, thermal management to regulate operating temperatures, and sophisticated algorithms to estimate battery state of health and remaining useful life.
This study aims to design a battery management system (BMS) on a Valve Regulated LeadAcid (VRLA) battery. The method used was the battery State of Charge (SOC) estimation using Coulomb Counting (CC) method. The results showed that the BMS was successfully designed and implemented to automatically cut-off the current when the SOC value is 100% (charging limit) and 20% (discharging limit)
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co-supervisor

PROXIMATE COMPOSITION, AMINO ACID PROFILE, CHEMICAL COMPOSITION, ANTIOXIDANT AND IN VITRO ANTI-DIABETIC ACTIVITIES OF Ocimum gratissimum STEM BARK EXTRACT

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Ocimum gratissimum is a widely recognized medicinal plant known for its diverse therapeutic properties, including antimicrobial, antioxidant, anti-inflammatory, and antidiabetic effects. Its rich content of bioactive compounds has made it a staple in traditional medicine for managing infections, digestive disorders, and general wellness. This study investigates the nutritional composition, amino acid profile, antioxidant potential, enzyme inhibitory activity, and phytochemical constituents of O. gratissimum stem extract, providing scientific insight into its medicinal relevance. The qualitative Proximate analysis showed high carbohydrate (53.69%), crude fiber (12.50%), and crude protein (12.26%) content with notable levels of moisture (7.40%), ash (6.27%) and crude fat content (4.92%). Amino acid profiling revealed abundant essential and non-essential amino acids, notably Isoleucine (29.42 mg/ml) and Alanine (22.55 mg/ml). In vitro Total Antioxidant Capacity assay demonstrated significant antioxidant activity, with ascorbic acid values increasing from 0.31 to 0.52 mg/ml as the concentration rose from 0.1 to 0.3 mg/ml, while the In vitro Nitric Oxide Scavenging Assay showed a progressive increase in the %NO Scavenging from 42.48% to 55.03% for concentrations of 0.1 to 0.3 mg/ml, confirming significant radical scavenging ability. The extract also showed strong alpha amylase (60.43%) and alpha glucosidase (76.91%) inhibition. GCMS identified 35 bioactive compounds, with Erucic acid (with a peak area of 4.59%), D-carvone (5.78%), Oleic Acid (8.90%), Cyclopropane (17.01%) and 9 borabicyclo compounds (28.30%), having the most prominent peak areas. These results suggest the extracts potential in nutritional and therapeutic applications.
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co-supervisor

THE USE OF Mangifera indica and Psidium guajava TO ASSESS THE LEVELS OF AIRBORNE TRACE METALS IN UGBOWO CAMPUS, UNIVERSITY OF BENIN

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The importance of tree plant species as biological components in the ecosystem is significant. These plants are used as shade, beautification, and even food. Urban locations are also bound to face numerous human activities that cause the introduction of many pollutants, including trace (heavy) metals into the environment. This research work is designed to determine the level of airborne trace metals (Cr, Fe, Ni, and Pb) present in the environment using Psidium guajava and Mangifera indica. The bark and leaf samples of these trees were collected, digested and analyzed using the Atomic Absorption Spectrometer (AAS). The bark samples of Mangifera indica gave a mean concentration of Cr – 0.24mg/kg, Fe – 15.85mg/kg, Ni – 0.11mg/kg, and Pb – 0.04mg/kg while the leaf samples gave a mean concentration of Cr – 0.28mg/kg, Fe – 15.70mg/kg, Ni – 0.09mg/kg, and Pb - 0.03mg/kg. Also, the data obtained from Psidium guajava bark samples gave a mean concentration of Cr – 0.19mg/kg, Fe – 2.25mg/kg, Ni – 0.03mg/kg, and Pb – 0.02mg/kg while the leaf samples resulted in a mean concentration of Cr – 0.15mg/kg, Fe – 2.70mg/kg, Ni – 0.06mg/kg, and Pb – 0.04mg/kg. The leaf and bark samples of Mangifera indica accumulated the highest level of trace metals, indicating that they are good biomonitors of airborne trace metals in Ugbowo Campus. The level of chromium (Cr) is above the permissible limit in all the plant species suggesting the contamination of the study area. The levels of other trace metals reported in this study are below the permissible limit. The findings of this work therefore shows that the study area is unsafe in Cr levels but safe and clean in the levels of other airborne heavy metals (Fe, Ni, and Pb).
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co-supervisor

A LEGAL ANALYSIS OF EUTHANASIA IN NIGERIA: BALANCING THE RIGHT TO LIFE AND THE RIGHT TO DIE

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The question of the existence of a right to die by euthanasia also referred to as mercy killing and assisted suicide is one that goes beyond national boundaries and diverse legal systems. The dominant legal regime around the world is that euthanasia and assisted suicide is unlawful and criminalized. However, with advancements in medical technology leading to remarkably greater ability to sustain and prolong human life far beyond what was previously thought possible, coupled with corresponding growth in human right law, many countries such as Belgium, Netherlands, etc. have legalized the acts of euthanasia and assisted suicide. There is no doubt that there is global acceptance of a right to life. The question that is the bedrock of the euthanasia controversy is whether or not there is also conversely a right to die. This paper explores whether a right to die could be inferred from constitutional guarantees of dignity and autonomy, particularly in cases of terminal illness or unbearable suffering. It evaluates global perspectives, contrasting Nigeria’s stance with jurisdictions where euthanasia is legalized under strict conditions, such as the Netherlands and Belgium. Ethical dilemmas, including patient autonomy, medical ethics, and societal implications, are critically assessed alongside potential legal reforms. The analysis highlights the absence of explicit euthanasia legislation in Nigeria and the judiciary’s limited engagement with the issue. Ultimately, the paper advocates for a balanced approach, proposing a national dialogue to address legal ambiguities while respecting Nigeria’s socio-cultural context, ensuring that any reform aligns with constitutional protections and human rights principles.
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THE INFLUENCE OF STRESS MANAGEMENT TECHNIQUES ON STUDENT ATHLETES PERFORMANCE AMONG SOCCER PLAYERS IN BENIN METROPOLIS

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This research investigated the stress management techniques, sports performance of student athletes among soccer players in Benin Metroplis. A correlation survey research design was employed in the study, five research questions were made in the study and four hypothesis were formulated. A sample of 135 soccer players were selected by multistage sampling procedure. The Instrument was validated by three experts, two from Department of Human Kinetics and sports science and one expert from the Department of Educational Evaluation and Counseling Psychology, all from the University of Benin. The Split-half method of reliability was used and a reliability index of 0.78 was obtained.
Data was analyzed using Descriptive statistics of Frequency units and Percentages while Pearson Product Moment Correlation Coefficient was used to analyzed the hypotheses. The findings of the study revealed that there is a significant relationship between stress relaxation technique and student- athlete sports performance, stress cognitive restructuring technique and student- athlete sports performance, stress exercise technique and student- athlete sports performance, stress goal setting technique and student- athlete sports performance. It was concluded that there is a significant relationship between stress management techniques and student- athlete sports performance. It was therefore recommended that sports psychologist should be attached to student- athlete to help manage their stress.
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co-supervisor

DESIGN AND FABRICATION OF A SOLAR ADSORPTION REFRIGERATION CYCLE

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The problem of electricity in Nigeria has become some sort of a nationwide pandemic that has plagued the country for years and continues to do so. With seemingly no end in sight to the electricity crisis, food storage has become very expensive as individuals as well as producers need to pay a lot of money to run generators to power refrigerators. An alternative means to this would be a more than welcomed development. This project aims to reduce the cost encountered in refrigeration by using vapor absorption refrigeration which is powered by solar energy.

The vapor absorption refrigerator uses water as its refrigerant, and zeolite is used as the absorbent. The compression system is a network of systems consisting of an absorber and a generator; aimed at compressing liquid refrigerant-absorbent mixture which requires less work to compress than vapor. The temperature of the evaporator, generator and condenser were measured and recorded periodically. The performance of the system is evaluated as the ratio of heat removed from the refrigerated space to the heat added to the system at the generator.
The refrigerator proved quite functional, achieving a COP of 0.66. This validates the functionality of the system but it was observed that it took 3 hours of heating to produce a 9°c drop (from 34.2°c to 25.2°c) in evaporator temperature. After 5 hours of heating, there was a 15°c drop (from 34.2°c to 19.2°c) in evaporator temperature. However, the atmospheric temperature was 27°c which means the cooling achieved was not appreciable. The system used in this project suffered from a lot of leakages and heat loss which directly affected the performance of the system. We recommend that further studies on techniques which would prevent heat loss and meticulous fabrication process to prevent leakages allow. Significant reduction in heat loss would greatly improve the performance of the waste solar powered VARS thereby making it more viable and suitable for domestic and commercial usage
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