Water Treatment

OPTIMIZATION OF METHYLENE BLUE DYE FROM AQUEOUS SOLUTION USING ACTIVATEDD CARBON OBTAINED FROM COCONUT SHELLS

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Abstract
The influence of dye concentration, adsorbent dosage, and contact time on the % removal of methylene blue dye (textile effluent) from aqueous solution was optimized and evaluated using a three-variable Box-Behnken design (BBD) in combination with response surface methodology (RSM). Coconut shell was utilized to make the adsorbent, which was then activated with H3PO4 after being carbonized at 600°C for an hour. Three variables dye concentration (50–200 mg/l), adsorbent dosage (g/100 ml), and contact time (10–60 mins), were varied to treat the dye solution. The responses of the linear and quadratic models that were developed for % dye removal from aqueous solution were significantly influenced by all three parameters, according to a statistical analysis of the data with p < 0.0001, the models were significant and demonstrated a strong fit with the experimental data. The adsorbent dosage and contact time had a positive impact on the percentage of dye removal. The process was optimized, and the maximum dye removal of 82% was attained at optimum dye concentration, adsorbent dosage, and contact time of 125 mg/l, 0.55 g/100 ml, and 35 min
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ASSESSMENT OF BOILING AS A WATER PURIFICATION METHOD AND COMPARATIVE ANALYSIS OF DOMESTIC WATER TREATMENT OPTIONS IN RURAL COMMUNITIES: A CASE STUDY OF OBAZAGBON COMMUNITY, BENIN CITY, EDO ST

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In rural areas, water contamination remains a major public health concern, exposingresidents to chemical and microbiological pollutants that can cause severe illnesses. Many households rely on untreated water sources such as wells, boreholes, and rivers, which often contain pathogenic microorganisms and elevated levels of heavy metals exceeding recommended safety limits. This study evaluates boiling as a low-cost, effective domestic water purification method, alongside other household treatment options such as filtration, coagulation, chemical disinfection, and distillation. Water samples were collected from the Obazagbon Community and analyzed in the laboratory to assess physico-chemical and microbiological parameters both before and after treatment. A multi-criteria decision analysis (MCDA) framework was applied to rate each purification method based on cost, effectiveness, feasibility, simplicity, sustainability, and accessibility. The results demonstrated that boiling significantly reduced microbial contamination, including total coliforms and E. coli, bringing bacterial counts well within the acceptable limits set by WHO and NSDWQ. Specifically, total coliform counts decreased from 149 CFU/ml (Sample A) and 153 CFU/ml (Sample B) to non-detectable levels, and E. coli was completely eliminated from the treated samples. In terms of chemical pollutants, boiling had limited impact. Levels of dissolved metals such as zinc (1.738 mg/L initially reduced to 1.520 mg/L), iron (0.798–0.801 mg/L), cadmium (0.015–0.018 mg/L), and lead (0.063–0.065 mg/L) remained largely unchanged after boiling, highlighting that thermal treatment primarily targets microbial contaminants and cannot remove dissolved chemical pollutants. Physicochemical parameters such as pH remained within safe limits (6.20–6.23 post-treatment). The persistence of metals is attributable to the geological composition of water sources and potential contamination from human activities, including agricultural runoff, poor waste management, and corroded plumbing systems. Overall, the study confirms that boiling is a highly effective method for microbial disinfection
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co-supervisor

THE OPTIMIZATION OF THE PERFORMANCE OF GRANULATED GROUNDNUT AS A COAGULANT FOR WATER TREATMENT

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This study investigated the optimization of granulated groundnuts (Arachis hypogaea) as a natural coagulant for water treatment, compared with the conventional chemical coagulant, alum. The research was motivated by the increasing need for sustainable and eco-friendly water treatment methods, as chemical coagulants such as alum have been associated with high residual ion concentrations and potential health concerns. The study aimed to determine the optimal operational conditions—coagulant dosage, stirring speed, and flocculation time—that yield the best water quality in terms of turbidity, pH, conductivity, and total dissolved solids (TDS). Response Surface Methodology (RSM) using Design-Expert software was employed to model and optimize the coagulation process based on experimental data from jar tests.

For the granulated groundnut coagulant, optimal conditions were achieved at a stirring speed of 400 rpm, stirring time of 2.37 minutes, and dosage of 1.00 mg/L, resulting in predicted responses of pH 6.61, conductivity 221.98 µS/cm, TDS 121.30 mg/L, and turbidity 7.86 NTU. In comparison, alum showed its best performance at a stirring speed of 400 rpm, stirring time of 7.06 minutes, and dosage of 2.96 mg/L, yielding a pH of 6.50, conductivity of 1392.24 µS/cm, TDS of 825.65 mg/L, and turbidity of 4.93 NTU. While alum produced slightly lower turbidity, it significantly increased conductivity and TDS, indicating higher residual salts and poorer overall water quality compared to granulated groundnut.

The findings demonstrate that granulated groundnut is an effective, biodegradable, and low-cost alternative to alum, providing satisfactory turbidity reduction, excellent ionic quality, and near-neutral pH at lower dosages and shorter flocculation times. The study concludes that groundnut-based coagulants can serve as a sustainable option for small-scale and rural water purification systems and recommends further research on microbial removal efficiency and large-scale application to enhance practical adoption in eco-friendly water treatment.
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co-supervisor