INVESTIGATING

INVESTIGATING SOME THERMAL, MECHANICAL, AND MICROSTRUCTURE BEHAVIOUR OF ALUMINUM-EGGSHELL COMPOSITE WARES

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Abstract
This study investigates the potential of eggshell waste as a reinforcement material in aluminum matrices for kitchenware applications, aiming to enhance material properties. Composites were fabricated with 7%, 10%, and 13% eggshell reinforcement and subjected to tensile testing, Brinell hardness testing, Differential Scanning Calorimetry (DSC), Scanning Electron Microscopy (SEM), and Energy-Dispersive Spectroscopy (EDS) to assess mechanical, thermal, and microstructural properties. Tensile testing revealed a significant increase in Ultimate Tensile Strength (UTS) with 13% reinforcement, reaching 134.29 MPa, though ductility was reduced. SEM analysis of the 10wt% composite showed a finer textured structure but non-uniform particle distribution. EDS confirmed calcium presence, and showed reduced oxygen content. Brinell hardness exhibited a positive correlation between the weight percentage of eggshell in the aluminum composite, which showed that higher eggshell content within the tested range leads to increased hardness. DSC indicated that eggshell addition altered thermal characteristics, with the 13wt% composite showing a slightly higher melting temperature and changes in heat of fusion. These results demonstrate that eggshell reinforcement enhances the tensile strength, hardness and modifies the thermal behaviour of aluminum
Supervisor(s)
co-supervisor

INVESTIGATING THE EFFECTS OF NANOSILICA ON SOME MECHANICAL PROPERTIES OF CONCRETE

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Abstract
This study investigated the effect of nanosilica (NS) as a partial replacement for ordinary Portland cement (OPC) on the mechanical and durability properties of concrete. The aim was to assess the suitability of nanosilica in improving concrete performance and to determine its optimum replacement level for sustainable construction applications in Nigeria.Concrete was produced using a nominal mix ratio of 1:2:4 and a constant water–cement ratio of 0.5. Nanosilica was used to replace cement at levels of 0%, 1%, 2%, and 3% by weight. Tests carried out included slump test, setting time determination, compressive strength test, flexural strength test, and water absorption test. Statistical analysis of the results was performed using oneway analysis of variance (ANOVA).Results showed that workability increased with increasing nanosilica content, while both initial and final setting times decreased. Compressive and flexural strengths increased up to an optimum nanosilica content of 2%, where 28-day values of 24.4 N/mm² and 5.25 N/mm² were recorded, compared to 22.5 N/mm² and 4.67 N/mm² for the control mix. Water absorption reduced to 7.3% at 2% nanosilica replacement compared to 9.7% for the control, indicating improved durability. ANOVA results showed no significant differences in compressive strength, flexural strength, and workability (p > 0.05), while setting time showed significant variation (p < 0.05). The study concluded that 2% nanosilica replacement provided the best overall performance and is recommended for producing stronger and more durable concrete
Supervisor(s)
co-supervisor