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Abstract
The surface free energy of nanoparticles is important as it gives us vital information about the reactivity and stability of nanoparticles. Starting from a previously reported equation, a theoretical model that involves a specific term for calculating the cohesive energy of nanoparticles, is established in a view to describe the surface free energy of metallic nanoparticles ( using different shapes of particle; sphere, cube and disk). The results show that the behaviour of surface free energy for spherical nanoparticles is the most realistic shape compared to disk and cubic shaped nanoparticles. As the surface free energy differs from shape to shape we also see that its value falls as the number of atoms (nanoparticle size) decreases. The results are in close agreement with the results of Fathi and Ayyad (2014).
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